Pd-Catalyzed Amination Oxidant

Works under air at rt

This system enables amination oxidation of electron-rich olefins with anilines under air at room temperature in ionic liquids, using H2O2 as the oxidant and oxygen source.

Yongpeng, Zheng · Yaodan, Wu · Li, Jianxiao · Wu, Wanqing · Yang, Shaorong · Qi, Chaorong · Jiang, Huanfeng

Green Chemistry 2025

Advantages

good yields

excellent regioselectivities

compatible with internal olefins