Bi-Based Double Perovskite Derived Halides

Bandgap tunable 2.0–2.9 eV

Continuous tuning of bandgap and luminescence behavior while maintaining non-centrosymmetric structures by varying halide, organic ligand, and alkali metal.

Chen, Jian · Liu, Yang · Congcong, Chen · Pan, Xin · Yin, Jun · Mao, Lingling

Angewandte Chemie - International Edition 2023

Advantages

15 Bi-based double perovskite derived halides

Bandgap tunable from 2.0 to 2.9 eV

PL intensity of bromide phases increases with decreasing temperature

PL intensity of iodide phases changes nonmonotonically with temperature

Selected non-centrosymmetric materials show different particle-size-dependent SHG trends