Pt₁/MoS₂ Single-Atom Catalyst

Acid-free methoxycarbonylation

A pocket-like Mo-S-Pt₁-S-Mo ensemble on MoS₂ enables ethylene methoxycarbonylation without liquid acid, outperforming reported heterogeneous catalysts by an order of magnitude.

Wang, An · Zhang, Leilei · Zhounan, Yu · Zhang, Shengxin · Li, Lin · Ren, Yujing · Liu, Xiaoyan · Liu, Wei · Yang, Xiaofeng · Zhang, Tianyu · Wang, Aiqin

Journal of the American Chemical Society 2023

Specifications

MP production rate

{'zh': '0.35', 'en': '0.35'} gMP gcat⁻¹

MP selectivity

{'zh': '91.1', 'en': '91.1'} %

MPa CO

{'zh': '0.70', 'en': ''} gMP gcat⁻¹

TOF

{'zh': '320.1', 'en': '320.1'} molMP molPt⁻¹