Ni-Fe/MC12A7 Dry Reforming Catalyst

Lattice oxygen lowers onset

A Ni-Fe bimetallic catalyst on an MCM-41 composite C12A7-O²⁻ support that uses lattice oxygen to promote CH₄ oxidation and trace water to accelerate methane dissociation in greenhouse gas dry reforming.

Huang, Lingxiang · Ma, Yue · Mufan, Niu · Ren, Shenyong · Guo, Qiaoxia · Xu, Chunming · Shen, Baojian

Applied Catalysis B: Environmental 2023

Advantages

CO mainly from ¹³CHx oxidation

DH from CHx and D₂O reaction

lattice oxygen promotes CHₓ oxidation

water accelerates methane conversion