Metal-Coordinatable
By introducing phosphine groups onto the silicon cubane framework, it can act as a bidentate ligand and undergo selective oxidative addition with Cu(I) to form a bis(silyl)copper complex.
Li, Yang · Cui, Chunming
Inorganic Chemistry 2023
Reaction with 2 equiv CuCl leads to selective oxidative addition to form bis(silyl)copper complex
Copper cation adopts a unique square-planar four-coordinate geometry