Phosphorus-Ligated Ni Cocatalyst

4.7× H₂O₂ yield under visible light

Atomic phosphorus ligands tune Ni 3d orbitals to suppress O-O cleavage and H₂O₂ decomposition, enabling efficient visible-light H₂O₂ photosynthesis in pure water.

Zou, Yunjie · Dongdong, Chu · Dayu, Sun · Chu, Wenhai · Ling, Lan

Science Bulletin 2025

Specifications

产量提升

{'zh': '4.7', 'en': ''} 倍

Advantages

Reverses H₂O₂ decomposition observed in Ni/PTI

Phosphorus ligands reconfigure Ni 3d orbital distribution