Stable deep-blue single-peak emission
Mg2+ incorporation at the B-site simultaneously induces spectral blueshift and phase homogenization, effectively suppressing halide migration inherent in mixed-halide blue perovskites to yield stable deep-blue electroluminescence.
Li, Nan · Xia, Yu · Xiao-Ying, He · Li, Jia · Wang, Kai · Chen, Jing · Chen, Chun · Huang, Lei · Yu-Tong, Yang · Chen, Xin · Yan-Hui, Lou · Wang, Zhaokui
Advanced Materials 2025
The pure-bromide system without halogen mixing eliminates ion migration at the root, ensuring stable emission wavelength.
B-site Mg doping facilitates energy transfer from small-n to large-n phases, homogenizing the phase and yielding unimodal emission.
First systematic investigation and mechanistic elucidation of the origin of bimodal emission in blue PeLEDs, guiding future design to avoid it.