High energy storage density
High-entropy relaxor ferroelectric ceramic achieving both high energy storage density and high efficiency through tolerance factor tuning.
Jielin, Zha · Jiayue, Liu · Lü, Xiaomei · Hu, Xueli · Zijing, Wu · Zhou, Min · Huang, Fengzhen · Ying, Xuenong · Zhu, Jinsong
Journal of Alloys and Compounds 2026
A recoverable energy storage density of 7.5 J/cm³ is achieved because the substitution of Na⁺ by K⁺ with larger radius increases the tolerance factor and tetragonality, thereby enhancing polarization.
Energy storage efficiency is 87%, and the ceramic exhibits good temperature, frequency, and fatigue stability, along with high power density and fast charge-discharge rates.
Adjusting the A-site Bi, K, and Na ratios continuously tunes the tolerance factor, enabling systematic optimization of properties.