Ordered vacancies boost ion transport
Controlled introduction of ordered structural vacancies via a co-reactant method enhances ion transport, alleviates Mn3+ Jahn-Teller distortion, and improves cycling and rate performance.
Gao, Chongwei · Chen, Ming · Li, Jiantao · Xunan, Wang · Zhang, Guobin · Xi, Tan · Shuhua, Zhang · Feng, Guang · Zhai, Dengyun · Kang, Feiyu
Energy and Environmental Sciences 2024
Ordered structural vacancies promote ion transport
Reduce interaction between host ions and framework
Alleviate Jahn-Teller distortion of Mn3+
Stable dynamic process of interface reaction