BiV₁₋ₓOy/Au Nanoparticle Domains

High glycerol oxidation selectivity

Reverse charge transfer modulates the Bi p-band center, enhancing adsorption and activation of secondary hydroxyl groups for efficient photoelectrochemical glycerol oxidation to dihydroxyacetone.

Wang, Zhonghao · Gao, Yuan · Park, Jung-bum · Hwang, Yun-jeong · Zongkun, Bian · Xia, Yong · Qiao, Botao · Zhang, Kan · Park, Jong Hyeok

Journal of the American Chemical Society 2025

Specifications

产率

{'zh': '470.5', 'en': ''} mmol m⁻²

选择性

{'zh': '75.2', 'en': ''} %

Advantages

Photocurrent density 5.5 mA cm⁻² at 1.23 V vs RHE

Applicable to noble metals Pt, Pd, and Ir