≈40× H₂ Evolution
Couples infrared irradiation with lattice vibrations to activate the n→π* electronic transition, markedly prolonging the lifetime of photocatalytically active charges for highly efficient visible-light water splitting.
Jiang, Daochuan · Hu, Shaonian · Yi, Qu · Tian, Xu · Du, Haiwei · Zhu, Chuhong · Zhongjun, Li · Yin, Lisha · Yuan, Yupeng · Liu, Gang
Advanced Functional Materials 2024
Two prominent vibration modes at 219 and 737 cm⁻¹ promote corrugation of tri-s-triazine units and induce n→π* transition
fs-TAS confirms n→π* transition prolongs lifetime of shallow electron trapping states and charge separation states