Bifunctional Chimeric Peptide DNAzyme

Dual CAT and POD activity

An artificial green catalyst made of peptide, DNA and hemin that decomposes hydrogen peroxide and degrades dyes simultaneously, outperforming the natural bifunctional enzyme KatG.

Qiu, Dehui · Zhang, Xiaobo · Tian, Fan · Liu, Yuan · He, Fangni · 72856381 · Wei, Shijiong · Mergny, Jean-Louis · Monchaud, David · Zhang, Shujuan · Ju, Huangxian · Zhou, Jun

National Science Review 2026

Advantages

Turnover number (kcat) of optimized bi-CPDzyme prototype (G-quadruplex-Hemin-HRRHKHRRH) surpasses natural CAT/POD bifunctional enzyme KatG

Competes with individual CAT and POD enzymes

Achieves efficient decomposition of bleaching-derived residual H2O2 in water-/energy-saving manner

Degrades dyes from textile industry effluents even in complex real samples

Easily recyclable and implementable