Phosphonium Ylide-fused Heteroarenes

NLO performance rivaling C60

Heteroarenes fused with a phosphonium cyclopentadienylide moiety display ylidic character up to 84%, leading to excellent nonlinear optical and optical limiting performances.

Zhang, Kaihua · Xiaofeng, Wang · Zhiruo, Zhou · Guo, Jing · Liu, Hao · Zhai, Yaxin · Yao, Yifan · Yang, Kun · Zeng, Zebing

Angewandte Chemie - International Edition 2025

Specifications

叶立德特征值高
{'zh': '84', 'en': ''} %

Advantages

NLO responses and OL performances comparable to or exceeding those of C60

One-pot synthesis with modular tuning of optical absorptions and redox properties