Cationic Covalent Organic Nanosheets

Selective CO₂-to-methanol

Ultrathin cationic covalent organic nanosheets based on cobalt phthalocyanine achieve highly selective electrochemical methanol synthesis via quaternary iminium groups, offering a new platform for multi-electron CO₂ reduction to methanol.

Song, Yun · Su, Jianjun · Huang, Libei · Guo, Weihua · Liu, Yong · Li, Gang · Xin, Yinger · Zhang, Qiang · Siwei, Zhang · Feng, Xing · Yang, Dengtao · Ravi, Sai Kishore · Zhong Tang, Ben · Ye, Ruquan

Advanced Materials 2023

Specifications

流动池中

{'zh': '-0.78', 'en': ''} V

串联器件中甲醇全局法拉第效率

{'zh': '54', 'en': ''} %

Advantages

Methanol partial current density improved by 711% over pristine CoTAPc

Improved by 270% over neutral imine-CONs